Heterogeneity Assessment Based on Average Variations of Morphological Tortuosity for Complex Porous Structures Characterization
DOI:
https://doi.org/10.5566/ias.2370Keywords:
geodesic distance transform, heterogeneity, Monte Carlo algorithms, morphological tortuosity, multi-scale porous networkAbstract
Morphological characterization of porous media is of paramount interest, mainly due to the connections between their physicochemical properties and their porous microstructure geometry. Heterogeneity can be seen as a geometric characteristic of porous microstructures. In this paper, two novel topological descriptors are proposed, based on the M-tortuosity formalism. Using the concept of geometric tortuosity or morphological tortuosity, a first operator is defined, the H-tortuosity. It estimates the average variations of the morphological tortuosity as a function of the scale, based on Monte Carlo method and assessing the heterogeneity of porous networks. The second descriptor is an extension, named the H-tortuosity-by-iterativeerosions, taking into account different percolating particle sizes. These two topological operators are applied on Cox multi-scale Boolean models, to validate their behaviors and to highlight their discriminative power.
References
Adler PM (1992). Porous media: geometry and
transports. Butterworth-Heineman, Boston, MA,
Adler PM, Thovert J-F (1998). Real porous media:
Local geometry and macroscopic properties. Appl
Mech Rev 51(9):537–585.
Baddeley A, Jensen EBV (2004). Stereology for
statisticians. Mg Stat Pro 103:03.
Balberg I, Anderson CH, Alexander S, Wagner N
(1984). Excluded volume and its relation to the
onset of percolation. Phys Rev B 30(7):3933.
Barman S, Rootzén H, Bolin D (2019). Prediction
of diffusive transport through polymer films from
characteristics of the pore geometry. AIChE J
(1), 446–57.
Batista ATF, Baaziz W, Taleb A-L, Chaniot J,
Moreaud M, Legens C, Aguilar-Tapia A, Proux
O, Hazemann J-L, Diehl F, Chizallet C, Gay A-S,
Ersen O, Raybaud P (2020). Atomic scale insight
into the formation, size and location of platinum
nanoparticles supported on g-alumina. ACS Catal
(7):4193–204.
Berrocal CG, Löfgren I, Lundgren K, Görander N,
Halldén C (2016). Characterisation of bending
cracks in R/FRC using image analysis. Cement
Concrete Res 90:104–16.
Bini F, Pica A, Marinozzi A, Marinozzi F (2019).
A 3D Model of the Effect of Tortuosity and
Constrictivity on the Diffusion in Mineralized
Collagen Fibril. Sci Rep-UK 9(1):2658.
Borgefors G (1986). Distance transformations in
digital images. Comput Vision Graph 34(3):344–
Bortolussi V, Figliuzzi B, Willot F, Faessel M, Jeandin
M (2018). Morphological modeling of cold spray
coatings. Image Anal Stereol 37(2):145–58.
Caflisch RE (1998). Monte Carlo and quasi-Monte
Carlo methods. Acta Numer 7:1–49.
Carman PC (1937). Fluid flow through granular beds.
Trans Inst Chem Eng 15:150–66.
Chaniot J, Moreaud M, Sorbier L, Becker J-M, Fournel
T (2019). Tortuosimetric operator for complex
porous media characterization. Image Anal Stereol
(1):25–41.
Chiu SN, Stoyan D, Kendall WS, Mecke J (2013).
Stochastic geometry and its applications. John
Wiley & Sons.
Clennell MB (1997). Tortuosity: a guide through the
maze. Geol Soc Spec Publ 122(1):299–344.
Criminisi A, Sharp T, Rother C, Pérez P (2010).
Geodesic image and video editing. ACM T
Graphic 29(5):134–1.
Decker L, Jeulin D, Tovena I (1998). 3D
morphological analysis of the connectivity of
a porous medium. Acta Stereol 17(1).
Dullien FAL (1979). Porous media: fluid transport and
pore structure. Academic press.
Ghanbarian B, Hunt AG, Ewing RP, Sahimi M (2013).
Tortuosity in porous media: a critical review. Soil
Sci Soc Am J 77(5):1461–77.
Ghanbarian B, Hunt AG, Sahimi M, Ewing RP,
Skinner TE (2013). Percolation theory generates
a physically based description of tortuosity in
saturated and unsaturated porous media. Soil Sci
Soc Am J 77(6):1920–29.
Gouéré J-B, Théret M (2017). Positivity of the time
constant in a continuous model of first passage
percolation. Electron J Probab 22.
Graham D (1957). Geometric heterogeneity in the
adsorption of nitrogen on graphitized carbon
surfaces. J Phys Chem-US 61(10):1310–13.
Grujicic M, Cao G, Roy WN (2004). A computational
analysis of the percolation threshold and the
electrical conductivity of carbon nanotubes filled
polymeric materials. J Mater Sci 39(14):4441–9.
Hill R (1963). Elastic properties of reinforced solids:
some theoretical principles. J Mech Phys Solids
(5):357–72.
Hollewand MP, Gladden LF (1995). Transport
heterogeneity in porous pellets—I. PGSE NMR
studies. Chem Eng Sci 50(2):309–26.
Holzer L, Wiedenmann D, Münch B, Keller L, Prestat
M, Gasser Ph, Robertson I, Grobéty B (2013). The
influence of constrictivity on the effective transport
properties of porous layers in electrolysis and fuel
cells. J Mater Sci 48(7):2934–52.
Jean A, Jeulin D, Forest S, Cantournet S, N’Guyen
F (2011). A multiscale microstructure model of
carbon black distribution in rubber. J Microsc
(3):243–60.
Jeulin D (1993). Damage simulation in heterogeneous
materials from geodesic propagations. Eng
Computation 10(1):81–91.
Jeulin D (1996). Modeling heterogeneous materials
by random structures. Invited lecture, European
Workshop on Application of Statistics and
Probabilities in Wood Mechanics, Bordeaux , N-
/96/MM, Paris School of Mines Publication.
Jeulin D (1997). Advances in Theory and Applications
of Random Sets. In : Advances In Theory And
Applications Of Random Sets: Proceedings Of The
Symposium. World Scientific 105.
Jeulin D, Moreaud M (2006). Percolation of
multi-scale fiber aggregates. S4G (Stereology,
Spatial Statistics and Stochastic Geometry) 6th
International Conference, Prague, Czech Republic.
Jeulin D (2010). Multi scale random models of
complex microstructures. Mater Sci Forum
:81–6.
Jeulin D (2012). Morphology and effective properties
of multi-scale random sets: A review. CR
Mecanique 340(4-5):219–29.
Kanit T, Forest S, Galliet I., Mounoury V., Jeulin
D. (2003). Determination of the size of the
representative volume element for random
composites: statistical and numerical approach. Int
J Solids Struct 40(13-14):3647–79.
Karimpouli S, Tahmasebi P (2019). 3D multifractal
analysis of porous media using 3D
digital images: considerations for heterogeneity
evaluation. Geophys Prospect 67(4):1082–93.
Kingman JFC (1993). Poisson Processes. Oxford
Science Publications, Oxford Studies in
Probability 3.
Lantuéjoul C, Beucher S (1981). On the use of the
geodesic metric in image analysis. J Microsc
(1):39–49.
Lohou C, Bertrand G (2005). A 3D 6-subiteration
curve thinning algorithm based on P-simple points.
Discrete Appl Math 151(1):198–228.
Matheron G (1975). Random sets and integral
geometry. Wiley New York.
Moreaud M, Chaniot J, Fournel T, Becker J-M, Sorbier
L (2018). Multi-scale stochastic morphological
models for 3D complex microstructures. 17th
Workshop on Information Optics (WIO), Quebec,
Canada, IEEE, 1–3.
Neumann M, Charry, EM, Zojer K, Schmidt V
(2020). On variability and interdependence of local
porosity and local tortuosity in porous materials: a
case study for sack paper. Methodol Comput Appl
–15.
Neumann M, Hirsch C, Stanˇek J, Beneš V, Schmidt
V (2019). Estimation of geodesic tortuosity and
constrictivity in stationary random closed sets.
Scand J Stat 46:848–84.
Neumann M, Abdallah B, Holzer L, Willot F, Schmidt
V (2019). Stochastic 3D Modeling of Three-
Phase Microstructures for Predicting Transport
Properties: A Case Study. Transport Porous Med,
–22.
Newman MEJ, Ziff RM (2001). Fast Monte Carlo
algorithm for site or bond percolation. Phys Rev
E 64(1):016706.
Neyman J (1934). On the two different aspects of
the representative method: the method of stratified
sampling and the method of purposive selection. J
R Stat Soc 97(4):558–625.
Ohser J, Ferrero C, Wirjadi O, Kuznetsova A, Duell
J, Rack A (2012). Estimation of the probability of
finite percolation in porous microstructures from
tomographic images. Int J Mater Res 103(2):184–
Petersen EE (1958). Diffusion in a pore of varying
cross section. AIChE J 4(3):343–5.
Peyrega C, Jeulin D (2013). Estimation of tortuosity
and reconstruction of geodesic paths in 3D. Image
Anal Stereol 32(1):27–43.
Raybaud P, Toulhoat H (2013). Catalysis by transition
metal sulphides: From molecular theory to
industrial application. Editions Technip.
Rigby SP, Gladden LF (1996). NMR and fractal
modelling studies of transport in porous media.
Chem Eng Sci 51(10):2263–72.
Rosenfeld A, Pfaltz JL (1968). Distance Functions on
Digital Pictures. Pattern Recogn 1:33–61.
Rutovitz D (1968). Data structures for operations on
digital images. Pictorial pattern recognition 105–
Saha PK, Borgefors G, Di Baja GS (2016). A survey on
skeletonization algorithms and their applications.
Pattern Recogn Lett 76:3–12.
Savary L, Jeulin D, Thorel A (1999). Morphological
analysis of carbon-polymer composite materials
from thick sections. Acta Stereol 18(3):297–303.
Serra J (1982). Image Analysis and Mathematical
Morphology. Academic Press, London.
Toivanen PJ (1996). New geodesic distance transforms
for gray-scale images. Pattern Recogn Lett
(5):437–50.
Tran V-D, Moreaud M, Thiébaut E, Denis L, Becker
J-M (2014). Inverse problem approach for the
alignment of electron tomographic series. Oil Gas
Sci Technol 69(2):279–91.
Van Brakel J, Heertjes PM (1974). Analysis of
diffusion in macroporous media in terms of a
porosity, a tortuosity and a constrictivity factor. Int
J Heat Mass Tran 17(9):1093–103.
Vogel H (2002). Topological characterization of
porous media. Morphology of condensed matter
–92.
Wang H, Pietrasanta A, Jeulin D, Willot F, Faessel
M, Sorbier L, Moreaud M (2015). Modelling
mesoporous alumina microstructure with 3D
random models of platelets. J Microsc 260(3):287–
Warren JE, Price HS (1961). Flow in heterogeneous
porous media. Soc Petrol Eng J 1(3):153–69.
Wernert V, Bouchet R, Denoyel R (2010). Influence of
molecule size on its transport properties through a
porous medium. Anal Chem 82(7):2668–79.
Willot F (2015) The power laws of geodesics in
some random sets with dilute concentration of
inclusions. ISMM 2015 535–46.
”plug im!” an open access and customizable
software for signal and image processing.
https://www.plugim.fr (2018).
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